江苏师范大学姚昌盛课题组招收有机专业研究生(接受调剂,达到国家线即可申请。)
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编辑:www.chinatiaoji.com
时间:2023-03-10
姚昌盛,江苏师范大学教授。
2002/09 - 2005/06,南开大学,元素有机化学国家重点实验室,理学博士,
1995/09 - 1998/06,苏州大学,化学化工学院,研究生,理学硕士,
1991/09 - 1995/06,徐州师范学院,化学系,大学本科,理学学士。
2012/11 - 2013/11,美国加州大学戴维斯分校(University of California, Davis),化学
系,访问学者,从事计算有机化学研究,导师:Dean J. Tantillo 教授
2008/09 - 2009/06,北京大学,分子与工程学院,访问学者,从事计算有机化学研究,导师:余志祥教授
2013/08 - 至今, 江苏师范大学,化学化工学院,教授
2006/07 - 2013/07,江苏师范大学,化学化工学院,副教授
2001/01 - 2006/06,徐州师范大学,化学化工学院,讲师
1998/08 - 2000/12,徐州师范大学,化学化工学院,助教
自参加工作以来,主要从事有机合成化学及理论有机化学研究。2010 年入选江苏省高校“ 青蓝工程” 优秀青年骨干教师。作为第一作者或通讯联系人,在《Org. Chem. Front.》、《Chem. Eur. J.》、《Org. Lett.》、《J. Org. Chem.》、《Org. Biomol. Chem.》、《Tetrahedron Lett.》、《Tetrahedron》、《J. Comb. Chem.》、《Synlett》、《Bioorg. Med. Chem. Lett.》、《J. Fluorine Chem.》、《J. Heterocyclic Chem.》和《中国化学》等国内外SCI 期刊上发表学术论文多篇。作为项目主持人,已经完成徐州市自然科学基金2项(XJ07065、XM09B016),江苏省高校自然科学研究重大项目1 项(09KJA430003),国家自然科学基金专项基金1 项(21242014)及国家自然科学基金面上项目一项(21372101)。现主持在研国家自然科学基金面上项目一项(21871113)。
我们实验室还有李团结教授(http://chem.jsnu.edu.cn/b6/5d/c15350a112221/page.htm)、张凯副教授(http://chem.jsnu.edu.cn/de/73/c15352a319091/page.htm)。
我们学院对调剂生的录取比例非常高,部分同学还在一年级获得二等以上的奖学金。学校提供100%覆盖的学业奖学金,我们实验室提供助研津贴。如果取得学术研究成果,另行奖励。此外,成绩优异者还可以荣获国家奖学金及研究生学业成果奖励。有意向者请发邮件至csyao@jsnu.edu.cn。来信必复。
部分近年来发表的学术论文:
1. Sun, Fang; Lu, Fangfang; Song, Xue; Wu, Wenchao; Zhang, Kai*; Yu, Chenxia; Li, Tuanjie; Wei, Donghui*; Yao, Changsheng*. Organic Chemistry Frontiers 2022, 9, 51-57.
2. Wang, Wenrong; Fu, Xiaoqing; Cai, Yuchen; Cheng, Li; Yao, Changsheng*; Wang, Xiangshan; Li, Tuan-Jie*. Pd(II)-Catalyzed Arylation/Oxidation of Benzylic C-H of 8-Methylquinolines: Access to 8-Benzoylquinolines. Journal of Organic Chemistry 2021, 86, 15423-15432.
3. Wu, Wenchao; Xu, Shuangli; Zhang, Yan; Wang, Xiu; Li, Ruotong; Sun, Fang; Yu, Chenxia; Li, Tuanjie; Wei, Donghui; Yao, Changsheng*. NHC-catalyzed β-specific addition of N-based nucleophiles to allenoates. Organic Chemistry Frontiers 2020, 7, 1593-1599.
4. Sun, Fang; Yin, Tingrui; Wang, Yang; Feng, Anni; Yang, Liuqing; Wu, Wenchao; Yu, Chenxia; Li, Tuanjie; Wei, Donghui; Yao, Changsheng*. A combined experimental and computational study of NHC-promoted desulfonylation of tosylated aldimines. Organic Chemistry Frontiers 2020, 7, 578-583.
5. Shi, Qianqian; Wang, Wei; Wang, Yang; Lan, Yu; Yao, Changsheng*; Wei, Donghui. Prediction on the origin of chemoselectivity in Lewis base-mediated competition cyclizations between allenoates and chalcones: a computational study. Organic Chemistry Frontiers 2019, 6, 2692-2700.
6. Sun, Fang; Yin, Tingrui; Feng, Anni; Hu, Yong; Yu, Chenxia; Li, Tuanjie; Yao, Changsheng*. Base-promoted regiodivergent allylation of N-acylhydrazones with Morita-Baylis-Hillman carbonates by tuning the catalyst. Organic & Biomolecular Chemistry 2019, 17, 5283-5293.
7. Cheng, Li; Sun, Yuqian; Wang, Wenrong; Yao, Changsheng*; Li, Tuan-Jie. Ligand-Free Copper(I)-Catalyzed Benzylic Acyloxylation of 2-Alkylpyridines under Aerobic Conditions. Journal of Organic Chemistry 2019, 84, 3074-3082.
8. Wang, Zhanlin; Zhang, Huiqing; Qian, Huimin; Wang, Yuanfeng; Yu, Chenxia; Li, Tuanjie; Yao, Changsheng*. An NHC-catalyzed, stereoselective α-functionalization of α,β-unsaturated carboxylic acids through in situ activation. Organic & Biomolecular Chemistry 2019, 17, 4564-4571.
9. Li, Sha; Tang, Ziwei; Wang, Yang; Wang, Dan; Wang, Zhanlin; Yu, Chenxia; Li, Tuanjie; Wei, Donghui; Yao, Changsheng*. NHC-Catalyzed Aldol-Like Reactions of Allenoates with Isatins: Regiospecific Syntheses of γ-Functionalized Allenoates. Organic Letters 2019, 21, 1306-1310.
10. Li, Sha; Yao, Yibiao; Tang, Ziwei; Sun, Baomin; Yu, Chenxia; Li, Tuanjie; Yao, Changsheng*. An enantioselective assembly of naphthopyran via NHC-catalyzed [3+3] annulation of bromoenal with β-tetralone. Organic & Biomolecular Chemistry 2019, 17, 268-274.
11. Hu, Yong; Li, Sha; Wang, Zhanlin; Yao, Yibiao; Li, Tuanjie; Yu, Chenxia; Yao, Changsheng*. NHC-Catalyzed Hetero-Diels-Alder Reaction of Allenoate with Chalcone: Synthesis of Polysubstituted Pyranyl Carboxylate. Journal of Organic Chemistry 2018, 83, 3361-3366.
12. Yu, Chenxia; Shen, Shide; Jiang, Ligen; Li, Jing; Lu, Yumiao; Li, Tuanjie; Yao, Changsheng*. NHC-catalyzed regiodivergent syntheses of difunctionalized 3-pyrazolidinones from α-bromoenals and monosubstituted hydrazines. Organic & Biomolecular Chemistry 2017, 15, 9149-9155.
13. Wang, Yuanfeng; Pan, Jian; Dong, Jingjiao; Yu, Chenxia; Li, Tuanjie; Wang, Xiang-Shan; Shen, Shide; Yao, Changsheng*. N-Heterocyclic Carbene-Catalyzed [4+2] Cyclization of Saturated Carboxylic Acid with o-Quinone Methides through in Situ Activation: Enantioselective Synthesis of Dihydrocoumarins. Journal of Organic Chemistry 2017, 82, 1790-1795 (highlighted by SYNFACTS, ESI highly cited paper).
14. Sun, Baomin; Gao, Lijiu; Shen, Shide; Yu, Chenxia; Li, Tuanjie; Xie, Yuanwei; Yao, Changsheng*. NHC-catalyzed [4+2] annulation of 2-bromo-2-enals with acylhydrazones: enantioselective synthesis of δ-lactams. Organic & Biomolecular Chemistry 2017, 15, 991-997.
15. Xie, Yuanwei; Yu, Chenxia; Que, Yonglei; Li, Tuanjie; Wang, Yuhong; Lu, Yinan; Wang, Wenjing; Shen, Shide; Yao, Changsheng*. N-Heterocyclic carbene-triggered transition-metal-free synthesis of 2,3-disubstituted benzofuran derivatives. Organic & Biomolecular Chemistry 2016, 14, 6463-6469.
16. Que, Yonglei; Lu, Yinan; Wang, Wenjing; Wang, Yuhong; Wang, Haotian; Yu, Chenxia; Li, Tuanjie; Wang, Xiang-Shan; Shen, Shide; Yao, Changsheng*. An Enantioselective Assembly of Dihydropyranones through an NHC/LiCl-Mediated in situ Activation of α,β-Unsaturated Carboxylic Acids. Chemistry - An Asian Journal 2016, 11, 678-681(封面文章).
17. Jia, Yanyan; Li, Tuanjie; Yu, Chenxia; Jiang, Bo; Yao, Changsheng*. A facile one-pot synthesis of 2,3-diarylated benzofurans via relay NHC and palladium catalysis. Organic & Biomolecular Chemistry 2016, 14, 1982-1987.
18. Que, Yonglei; Xie, Yuanwei; Li, Tuanjie; Yu, Chenxia; Tu, Shujiang; Yao, Changsheng*. An N-Heterocyclic Carbene-Catalyzed Oxidative γ-Aminoalkylation of Saturated Carboxylic Acids through in Situ Activation Strategy: Access to δ-Lactam. Organic Letters 2015, 17, 6234-6237.
19. Xie, Yuanwei; Yu, Chenxia; Li, Tuanjie; Tu, Shujiang; Yao, Changsheng*. An NHC-Catalyzed In Situ Activation Strategy to β-Functionalize Saturated Carboxylic Acid: An Enantioselective Formal [3+2] Annulation for Spirocyclic Oxindolo-γ-butyrolactones. Chemistry- A European Journal 2015, 21, 5355-5359.
20. Que, Yonglei; Li, Tuanjie; Yu, Chenxia; Wang, Xiang-Shan; Yao, Changsheng*. An enantioselective assembly of spirocyclic oxindole-dihydropyranones through NHC-catalyzed cascade reaction of isatins with N-hydroxybenzotriazole esters of α,β-unsaturated carboxylic acid. Journal of Organic Chemistry 2015, 80, 3289-3294.
21. Xie, Yuanwei; Que, Yonglei; Li, Tuanjie; Zhu, Ling; Yu, Chenxia; Yao, Changsheng*. N-heterocyclic carbene-catalyzed [4+2] cyclization of 2-bromo-2-enal with 3-alkylenyloxindoles: efficient assembly of spirocarbocyclic oxindole. Organic & Biomolecular Chemistry 2015, 13, 1829-1835.
22. Xiao, Zhaoxin; Yu, Chenxia; Li, Tuanjie; Wang, Xiang-Shan; Yao, Changsheng*. N-Heterocyclic Carbene/Lewis Acid Strategy for the Stereoselective Synthesis of Spirocyclic Oxindole-Dihydropyranones. Organic Letters 2014, 16, 3632-3635.
江苏师范大学化学与材料科学学院拥有400 MHz核磁共振仪、单晶衍射仪、高分辨质谱仪、液质联用仪等有机合成必备的仪器。我们实验室有专用的高效液相色谱仪、手套箱、光化学反应器等合成、分析仪器。此外,学校订购了SciFinder、ACS等数据库,科研的软硬件设施齐全。本课题组欢迎一切有识之士合作研究,同时也欢迎愿意从事有机专业的同学来我们实验室学习。本实验室的主要研究方向为氮杂环卡宾(NHC)催化的环状化合物的合成及理论有机化学。我们的信念是:英雄不问出处,做最好的自己,我们共同努力!每个学生,我们都会认真对待,保证愿意学习的学生从我们实验室毕业后,会查资料,会做实验,会写论文(或专利)。部分优秀的学生,会自己寻找研究课题。
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